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In 1776 the Caisse d Escompte was established and provided credit as low as 4% at short term By the end of the old regime, in 1789, the volume of rentes outstanding had increased enormously, but there was no record of nominal rates in excess of 5% This same rate of 5% was initially paid on the assignats of 1789 Their rate was reduced to 3% in 1790, but owing to their forced issue and heavy discounts, no market rate of interest can be read into their nominal rate In 1795 the government established a 6% legal maximum for commercial credit and a 5% legal maximum for credit secured by real estate (398).

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bond in the cis con guration (VIII) and on opposite sides in the trans con guration (IX), for example, for polyisoprene.

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When all of the double bonds in the polymer molecule have the same con guration, the result is two different ordered polymer structures transtactic and cistactic. Figure 8-5 shows the structures of the completely cis and completely trans polymers of isoprene. The stereochemistry of these polymers is indicated in their names. For example, the trans polymer (IX) is named as trans-1,4-polyisoprene or poly(E-1-methylbut-1-ene-1,4-diyl). The rst name is the IUPAC-recommended trivial name; the second name is the IUPAC structurebased (Sec. 1-2c) [IUPAC, 1966, 1981, 1996]. It should be noted that both carbon atoms of the double bond in VIII and IX are achirotopic stereocenters. Interchange of the groups attached to one or the other carbon of the double bond converts VIII into IX and vice versa. 8-1e 8-1e-1 1-Substituted and 1,4-Disubstituted 1,3-Butadienes 1,2- and 3,4-Polymerizations

The polymerizations of 1-substituted (X) and 1,4-disubstituted (XI) 1,3-butadienes involve several possibilities. 3,4-Polymerization of a 1-substituted 1,3-butadiene proceeds with the

Get familiar with the unit s functions (play all the games). Then follow the instructions for opening the original Speak & Spell, covered previously in Project 1 ( 14). I ll bet you guessed all that.

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Following the two-thirds bankruptcy of 1797 and as a part of Napoleon s financial reforms, the entire national debt was forcibly refunded into 5% rentes These rates were nominal interest rates of the revolutionary decade What were the market rates As might be expected following the political turbulence of this period, its destruction, its wars, its inflation, and its bankruptcies, the market prices of rentes were not very high A series of consecutive market quotations on rentes was begun in the year 1797 This was the year when two thirds of the income of the rentes was made payable in almost valueless land warrants It was the year of Napoleon s initial victories, a year when France had no firmly established government and was at war with most of Europe It was the year when Napoleon was expected momentarily to invade England (He invaded Egypt instead.

same possibilities as the polymerization of a monosubstituted ethylene such as propene. 1,2Polymerization of a 1-substituted 1,3-butadiene (Eq. 8-4) as well as 1,2- and 3,4-polymerizations of a 1,4-disubstituted 1,3-butadiene (Eqs. 8-5 and 8-6) proceed with the same possibilities as 1,2-disubstituted ethylene.

2-58

in which the initial hydroxyl group and carboxyl group concentrations are both [M]0. The concentration of ester groups [COO] at equilibrium is pe M 0 , where pe is the extent of reaction at equilibrium. pe M also represents [H2O] at equilibrium. The concentrations of hydroxyl and carboxyl groups at equilibrium are each ( M 0 pe M 0 ). The equilibrium constant for the polymerization is given by

) In 1797 the 5% rentes were quoted as fluctuating in price between 61 8 and 361 8 as a percent of 100 If their nominal rate of 5% is applied to these prices, the computed yields were 82 14% The mean price in 1798 was 165 8, and at this price the yield was 30% (403) if the government paid the interest, and 10% if it paid only one third of the interest In 1799, when Napoleon was established as First Consul for a ten-year term and began his reform of the government finances, the price of 5% rentes ranged from 221 2 high to 7 low; 143 4 was the mean Obviously, payment in full was not expected, or the medium of payment was not wanted In 1800 there was a sharp improvement in the price of rentes.

K pe M 0 2 COO H2 O COOH OH M 0 pe M 0 2 2-59

No surprises. Texas Instruments stuck to its internal layout quite rigorously, from the membrane-style Speak & Spell onward. Bending points are shown in Figure 17-2.

K p2 e 1 pe 2 2-60

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